Snow White is a young and innocent princess who appears as the central protagonist in Snow White and the Seven Dwarfs, the first feature-length animated Disney film ever made. Her beauty makes her a target of the evil Queen Grimhilde in Disney Heroes vs. Villains.
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On the orders of Queen Grimhilde, who envied the beauty of the princess Snow White, the voodoo witch doctor Facilier cornered her in a field of flowers. When Facilier tried to get Snow White to come with him, she fled into the nearby forest. Giving chase, Facilier used his voodoo powers to summon terrifying illusions to torment the princess. Snow White, overcome with so much fear, fainted, allowing Facilier to take her captive.
With the time of the sacrifice growing near, Maleficent looked over the princesses (Snow White, Aurora, and Cinderella) held in the dungeons of Forbidden Mountain to make sure that they were still safely imprisoned. Besides these three, the other princesses were held in her allies' strongholds so that none of the heroes could free them all at once.